2001: COSMOtherm & COSMO-RS publications Return to Index
COSMO-RS: A novel view to physiological solvation and partition questions
A Klamt, F Eckert, M Hornig - Journal of Computer-Aided Molecular Design, Volume 15, Number 4 / April, 2001, Pages 355-365, DOI 10.1023/A:1011111506388
Describes COSMO-RS as an integrated theory which combines the aspects of continuum solvation and surface interactions. The use of COSMO-RS for drug discovery and design is demonstrated by applications to blood-brain partition coefficients, and water solubility.
Validation of the COSMO-RS Method: Six Binary Systems
F Eckert, A Klamt - Ind. Eng. Chem. Res., 40 (10), 2371 -2378
Presents a validation of COSMO-RS predictions of activity coefficients and vapor pressures, applied to six binary mixtures for which recent accurate experimental vapor-liquid and liquid-liquid equilibria data are available.
C-N rotational barriers in aromatically substituted styrylformamides: an AM1 study utilizing the conductor like screening model for real solvents
C Threlfall - Journal of Molecular Structure: THEOCHEM, Volume 540, Number 1, 4 May 2001 , pp. 47-52(6)
AM1 semi-empirical calculations utilizing COSMO-RS are performed on a series of styrylformamides in their E, Z and transition state conformations to determine barriers to rotation (BIR) about the amide bond.
Prediction of phase equilibria for binary mixtures by molecular modeling
M Fermeglia, S Pricl, AIChE Journal, Volume 47, Issue 10 , Pages 2371 - 2382
Describes early applications of COSMO-RS in chemical engineering. It compares COSMO-RS with molecular mechanics/dynamics simulations, for estimating the PHSCT EOS parameters and for predicting VLE behavior for binary mixtures.